Preheat and prep: Preheat your oven to 375°F (190°C) and line a 12-cup muffin tin with paper liners. Proper prep is key to flawless Baileys St. Patrick’s Day cupcakes.
Mix dry ingredients: In a large bowl, whisk together 2 cups all-purpose flour, 2 cups sugar, 1 cup dark chocolate cocoa powder, 2 teaspoons baking powder, 1 teaspoon baking soda, 1 teaspoon espresso powder, and 1 teaspoon salt. Sifting the cocoa powder helps remove lumps and keeps your batter silky smooth.
Combine wet ingredients: Add 2 large room-temperature eggs, 1/2 cup vegetable oil, 1 teaspoon vanilla extract, and 1 cup Baileys Irish Cream to the dry ingredients. Use an electric mixer to beat until fully combined.
Add boiling water: Carefully add 1 cup boiling water (microwaving for about 2 minutes works fine) and mix thoroughly. Your batter will be very thin — that’s exactly what you want for a moist, tender cupcake.
Fill cupcake liners: Using a large spoon or small measuring cup, fill each paper liner just over halfway with batter. This ensures cupcakes bake evenly and don’t overflow.
Bake: Place in the preheated oven and bake for 20 minutes, or until a toothpick inserted in the center comes out clean.
Cool: Remove from the oven and transfer cupcakes from the pan to a wire rack to cool completely. Cooling is crucial so your frosting doesn’t melt.
Make Baileys buttercream frosting: In a large mixing bowl, beat 1 cup softened butter until creamy. Gradually add 5 cups sifted powdered sugar, 1/4 teaspoon salt, 1 teaspoon vanilla extract, and 2–3 tablespoons Baileys Irish Cream. Beat until smooth and fluffy, adjusting Baileys to taste for your perfect boozy flavor.
Frost cupcakes: Frost cooled cupcakes by hand with a spatula, or transfer the Baileys buttercream to a piping bag or zip-top bag fitted with a decorating tip. Decorate as desired — chocolate shavings, sprinkles, or green accents make them festive for St. Patrick’s Day.
Serve and store: Serve immediately for maximum indulgence. Leftovers can be stored in the refrigerator in an airtight container for a few days.